Clay
The term clay is applied to those fine grained earthy materials composed
of various minerals whose most prominent properties are:
- Plastic when wet,
- Capable of retaining of shape when dried,
- Formation of a hard rock-like mass without losing the originals contour when heated to red heat.
Formation: Clay is decomposed products of the igneous rocks
containing mainly alumina and silica, which by the action of the weathering
agencies are converted into plastic or semi plastic masses. When the parent
rock contain impurities like lime magnesia, iron etc, the final products are
the impure clays, but if the disintegration takes place from feldspathic rock
the residual clays are comparatively pure and we get white clay known as Kaolin. The precise manner in which
this decomposition occurs is still open to investigation. The basic rocks from
which clays are formed are complex aluminosilicates. During the weathering this
becomes hydrolysed, the alkali and alkaline earth ions from soluble salts and
are leached out. The remainder consists of hydrated aluminosilicates of varying
composition and structure and silica. The liberated silica is probably hydrated
and ultimately converted into crystalline form.
This process can be represented by the following chemical equations:
Hydrolysis: K2O.Al2O3.6SiO2
+ H2O => Al2O3.6SiO2 + K2CO3
|
Desilication: Al2O3.6SiO2
=> Al2O3.2SiO2 + 4SiO2
|
Hydration: Al2O3.6SiO2
+ H2O => Al2O3.2SiO2.2H2O
|
K2O.Al2O3.6SiO2
+ 2H2O => Al2O3.2SiO2.2H2O
+K2CO3 + 4SiO2
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